4-Methyl-N-(4-methylphenyl)benzamide
نویسندگان
چکیده
In the title compound, C(15)H(15)NO, the amide fragment has an anti conformation. The central amide group is tilted with respect to the benzoyl ring, forming a dihedral angle of 32.3 (5)°. The benzoyl and aniline rings make a dihedral angle of 59.6 (5)°. Mol-ecules are linked into infinite supra-molecular chains via N-H⋯O hydrogen bonds. The mol-ecule is disordered so that the aromatic rings are disposed across a twofold axis with equal occupancies.
منابع مشابه
4-Chloro-N-(3-methylphenyl)benzamide
In the title compound, C(14)H(12)ClNO, the meta-methyl substituent in the aniline ring is positioned anti to the N-H bond. The dihedral angle between the rings is 12.4 (1)°. The crystal structure is stabilized by inter-molecular N-H⋯O hydrogen bonds, which link the mol-ecules into C(4) chains running along the c-axis direction.
متن کاملN-(4-Methylphenyl)-N-{[(2-nitrophenyl)acetyl]oxy}benzamide
In the title mol-ecule, C(22)H(18)N(2)O(5), the nitro-substituted benzene ring makes dihedral angles of 71.56 (1)° with the benzoyl ring and 16.28 (1)° with the methyl-substituted benzene ring. The crystal structure features C-H⋯O inter-actions, which generate chains.
متن کامل3-Methyl-N-(4-methylphenyl)benzamide
In the title compound, C(15)H(15)NO, the two aromatic rings make a dihedral angle of 70.06 (3)°, while the central amide core -NH-C(=O)- is twisted by 30.24 (4) and 40.16 (3)° out of the planes of the 3-methyphenyl and 4-methyphenyl rings, respectively. The methyl groups are disordered over two equally occupied positions. In the crystal, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules ...
متن کامل2-Methyl-N-(4-methylphenyl)benzamide
The conformations of the N-H and C=O bonds in the structure of the title compound, C(15)H(15)NO, are trans to each other. Furthermore, the position of the amide O atom is syn to the ortho-methyl group in the benzoyl ring. The central amide group is tilted at an angle of 59.96 (11)° to the benzoyl ring, and the benzoyl and aniline rings form a dihedral angle of 81.44 (5)°. N-H⋯O hydrogen bonds l...
متن کاملN-(4-Methylphenyl)benzamide
The structure of the title compound, C(14)H(13)NO, resembles those of N-(2-chloro-phen-yl)benzamide, 2-chloro-N-phenyl-benzamide, N-(2,3-dichloro-phen-yl)benzamide, N-(3,4-dichloro-phen-yl)benzamide and 2-chloro-N-(2-chloro-phen-yl)benzamide with similar bond parameters. The benzene and methylphenyl rings have a dihedral angle of 63.41 (5)°, while the amide group makes a dihedral angle of 20.5 ...
متن کامل3-Chloro-N-(3-methylphenyl)benzamide
In the mol-ecular structure of the title compound, C(14)H(12)ClNO, the meta-Cl atom in the benzoyl ring is positioned syn to the C=O bond, while the meta-methyl group in the aniline ring is positioned anti to the N-H bond. The two aromatic rings make a dihedral angle of 77.4 (1)°. In the crystal, the molecules are linked by N-H⋯O hydrogen bonds, forming C(4) chains propagating in [010].
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009